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added additional info as this is the best answer, in my opinion, and there was a message from SE that the answer is too short
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TakeIf you really want to travel by train but still want to travel less than a day, then take a bus from Trieste bus station to Sezana and then a train from Sezana to Ljubljana. theThe train station in Sezana is right close to the bus onestation.

The alternative, and a longer option, is to take a bus to Koper (about 20km), and then a train from there to Ljubljana.

Take a bus from Trieste bus station to Sezana and then a train from Sezana to Ljubljana. the train station in Sezana is right close to the bus one.

If you really want to travel by train but still want to travel less than a day, then take a bus from Trieste bus station to Sezana and then a train from Sezana to Ljubljana. The train station in Sezana is right close to the bus station.

The alternative, and a longer option, is to take a bus to Koper (about 20km), and then a train from there to Ljubljana.

Notice added Needs detailed answers by Ankur Banerjee
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dArio
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Take a bus from Trieste bus station to Sezana and then a train from Sezana to Ljubljana. the train station in Sezana is right close to the bus one.