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This question already has an answer here:

What if I was granted with single entry schengen visa but I will not utilize it to enter any schengen state but only in Croatia, is it possible?.

I will pass only a schengen state as connecting flight going to Croatia e.g. from my origin country to Germany as my connecting to my flight to Croatia and then vice versa.

marked as duplicate by Henning Makholm, Ali Awan, Daniil, Uciebila, Jim MacKenzie Sep 6 at 19:39

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No, you cannot do this. A single-entry Schengen visa is not valid for entry into Croatia, regardless of whether or not it has been or will be used in the Schengen area.

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