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San Gil is on the way to Bucaramanga, so any bus leaving Bogotá may stop there. But of course in Colombia it is important to cross check in advance. I found a company called Berlinas that has a line: http://www.berlinasdelfonce.com/index.php?option=com_content&view=article&id=80&Itemid=5 Recorrido (route): Bogotá, Tunja, Barbosa, ...
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